Peripheral halogenation engineering controls molecular stacking to enable highly efficient organic solar cells

Yalu Zou; Hongbin Chen; Xingqi Bi; Xiaoyun Xu; Hebin Wang; Menglu Lin; Zaifei Ma; Mingtao Zhang; Chenxi Li; Xiangjian Wan; Guankui Long; Yao Zhaoyang; Yongsheng Chen

doi:10.1039/D2EE01340A

Peripheral halogenation engineering controls molecular stacking to enable highly efficient organic solar cells†

Yalu Zou,

‡^a Hongbin Chen,‡^a Xingqi Bi,^a Xiaoyun Xu,^b Hebin Wang,^c Menglu Lin,^c Zaifei Ma,

^b Mingtao Zhang,

^a Chenxi Li,^a Xiangjian Wan,

^a Guankui Long,

^cd Yao Zhaoyang

*^a and Yongsheng Chen

*^a

Author affiliations

* Corresponding authors

^a The State Key Laboratory and Institute of Elemento-Organic Chemistry, Centre of Nanoscale Science and Technology, Key Laboratory of Functional Polymer Materials, Renewable Energy Conversion and Storage Center (RECAST), College of Chemistry, Nankai University, Tianjin 300071, China
E-mail: zyao@nankai.edu.cn, yschen99@nankai.edu.cn

^b The State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, Center of Advanced Low-Dimension Materials, College of Materials Science and Engineering, Donghua University, Shanghai, China

^c The National Institute for Advanced Materials, Renewable Energy Conversion and Storage Center (RECAST), College of Materials Science and Engineering, Nankai University, Tianjin, China

^d The State Key Laboratory of Luminescent Materials and Devices, South China University of Technology, Guangzhou, China

Abstract

The diverse molecular stacking tuned by peripheral halogens in non-fullerene acceptors (NFAs) significantly affects the molecular physicochemical properties, the film morphologies and thus the power conversion efficiencies (PCEs) of organic solar cells (OSCs). Despite the crucial role of peripheral halogens, few explorations have been performed to bridge peripheral halogenation with molecular stackings and device performances, especially for the state-of-the-art Y-series. Herein, a series of high-efficient NFAs, CH-6F, CH-4Cl and CH-6Cl, are constructed with the same backbone but different peripheral halogenations in both conjugate extended central units and end groups. Single-crystal analysis indicates that CH-6F possesses similar molecular packings to Y6; however, CH-4Cl and CH-6Cl with chloro-substitutions demonstrate several quite unique packing modes of end unit to central unit, etc. Compared with CH-6F and Y6, CH-4Cl and CH-6Cl possess greatly reduced electron reorganization energies and shorter intermolecular packing distances, and exhibit more balanced charge mobilities, better phase separation, and lower energy disorders when blended with the PM6 donor. Furthermore, the reduced energy offsets between charge transfer and local exciton states for CH-4Cl and CH-6Cl result in an enhanced hybridization of these two states and thus suppress the non-radiative recombination losses in OSCs. Consequently, high-efficient OSCs are afforded by utilizing CH-series NFAs with a champion PCE of 18.22% and a markedly reduced ΔV_nr of 0.203 V in CH-4Cl-based ternary devices. Our study reveals that such a slight modification of peripheral halogens could cause quite different but superior intermolecular packings, rendering peripheral halogenation engineering as an effective strategy to further boost PCEs of high-performance OSCs through delicate molecular stacking control.

Energy & Environmental Science

Peripheral halogenation engineering controls molecular stacking to enable highly efficient organic solar cells†

Abstract

Associated articles

Supplementary files

Article information

Download Citation

Permissions

Peripheral halogenation engineering controls molecular stacking to enable highly efficient organic solar cells

Social activity

Search articles by author

Spotlight

Advertisements