The aim of this study was to develop a new method for sampling and analyzing polycyclic aromatic hydrocarbons in the air. This was achieved by utilizing a needle trap device packed with a modified porous aromatic framework coated with magnetic nanoparticles (PAF-6-MNPs). The modified adsorbent underwent qualitative evaluation using Fourier-transform infrared spectroscopy and X-ray diffraction, as well as scanning and transmission electron microscopy. The optimal conditions for sampling polycyclic aromatic hydrocarbons compounds were determined using a dynamic atmosphere chamber. The method was validated by taking various samples from the standard chamber, and then analyzed under different environmental sampling conditions using a gas chromatography device. The limit of detection (LOD) and limit of quantification (LOQ) values for the analytes of interest, including naphthalene, anthracene, and pyrene, ranged from 0.0034–0.0051 and 0.010–0.015 μg L⁻¹, respectively. Also, the repeatability and reproducibility of the method expressed as relative standard deviation, for the mentioned analyses were found to be in the range of 17.8–20.5% and 20–22.9%. The results indicated that over a 20 day storage period (with the needle trap device containing the analytes of interest kept in the refrigerator), there was no significant decrease in the amount of analytes compared to the initial amount. These findings suggest that, the needle trap packed with the proposed adsorbent offers a reliable, highly-sensitive, easy-to-use, and cost-effective method for sampling polycyclic aromatic hydrocarbons in the air compared to the conventional method recommended by the National Institute of Occupational Safety and Health (NIOSH), method 5515.