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Photophysics and dynamics of chromophores with a benzylidene imidazolinone core, responsible for emission of green fluorescent protein variants, were studied as a function of host topology by three approaches. Coordinative, non-coordinative, and “fastened” immobilization were utilized to study chromophore emission. Variable-temperature quadrupolar spin-echo 2H NMR spectra are reported.

Graphical abstract: A metal–organic framework as a flask: photophysics of confined chromophores with a benzylidene imidazolinone core

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