Dimethylallyl 2-indolyl sulphonium salts are shown to undergo thio-Claisen rearrangements readily: the possible role of this new reaction in indole alkaloid biosynthesis is described.
B. W. Bycroft and W. Landon, J. Chem. Soc. D, 1970, 967 DOI: 10.1039/C29700000967
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