Chloromethyl methyl sulphoxide reacts with alcohols, phenol, and thiophenols in the presence of potassium hydroxide to yield the corresponding displacement products, and several other α-chloro-sulphoxides undergo the SN2 substitution with MeS–.
K. Ogura and G. Tsuchihashi, J. Chem. Soc. D, 1970, 1689 DOI: 10.1039/C29700001689
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