Issue 2, 1971

Stereochemistry of additions of amines to the syn,syn-π-1,5-dimethylpentadienyliron tricarbonyl cation

Abstract

The reaction of amines with the title cation gives π-dienylamine–Fe(CO)3 complexes: n.m.r., c.d., and X-ray studies on the reaction products indicate a trans,trans- or cis,trans-co-ordination of the diene according to the basic strength of the amine.

Article information

Article type
Paper

J. Chem. Soc. D, 1971, 100-101

Stereochemistry of additions of amines to the syn,syn-π-1,5-dimethylpentadienyliron tricarbonyl cation

G. Maglio, A. Musco, R. Palumbo and A. Sirigu, J. Chem. Soc. D, 1971, 100 DOI: 10.1039/C29710000100

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