It is shown that a Δ8(14)-sterol is not involved in cholesterol biosynthesis; the removal of C-32 in sterols containing a double bond at either Δ7(8) or Δ8(9) is attended exclusively with the formation of 7,14-diene and 8,14-diene sterols, respectively.
K. T. W. Alexander, M. Akhtar, R. B. Boar, J. F. McGhie and D. H. R. Barton, J. Chem. Soc. D, 1971, 1479 DOI: 10.1039/C29710001479
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