Cyclic secondary amines have been selectively carbonylated to the N-formyl derivatives using ruthenium catalysts under homogeneous conditions and a carbon monoxide pressure of 1 atm.
J. J. Byerley, G. L. Rempel, N. Takebe and B. R. James, J. Chem. Soc. D, 1971, 1482 DOI: 10.1039/C29710001482
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