Issue 7, 1972

Pyran-2-ylidene carbene complexes

Abstract

Reaction of the cyclopropenylidene complexes (1) with pyridinium ylides gives stable pyran-2-ylidene complexes (3), a new type of carbene complex stabilised by 6π-electron delocalisation; some reactions of these complexes are described.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1972, 420-420

Pyran-2-ylidene carbene complexes

C. W. Rees and E. von Angerer, J. Chem. Soc., Chem. Commun., 1972, 420 DOI: 10.1039/C39720000420

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