New data for the rate of solvolysis of PhCH2Cl at 0 and 4 °C fit on the same Arrhenius plot as data at higher temperatures contradicting the sharp change in activation parameters reported by Hills and Viana; the solvent isotope effect at 4 °C is normal and changes in the aqueous solvent between 0 and 4 °C produce no marked effect on the reaction rate of either PhCH2Cl or CMe3Cl.
W. J. Albery and J. S. Curran, J. Chem. Soc., Chem. Commun., 1972, 425 DOI: 10.1039/C39720000425
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...