Bromination of semibullvalene proceeds with stereoselective cis,exo-1,4-addition in contrast to bullvalene where kinetically controlled trans-1,4-addition occurs.
L. A. Paquette, G. H. Birnberg, J. Clardy and B. Parkinson, J. Chem. Soc., Chem. Commun., 1973, 129 DOI: 10.1039/C39730000129
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