Shaken cultures of Willia anomala Hansen convert tyramine (1) and hordenine (2) into tyrosol (3) through a process involving non-stereospecific hydrogen removal from the position α to the nitrogen, followed by hydrogen addition, which, in the case of tyramine (1), proceeds with the introduction of a pro-R hydrogen atom.
C. Fuganti, D. Ghiringhelli, P. Grasselli and A. Santopietro-Amisano, J. Chem. Soc., Chem. Commun., 1973, 862 DOI: 10.1039/C39730000862
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