The isobutane chemical-ionization mass spectra of deuterium-labelled model compounds show that fragmentation can occur at locations remote from the site of protonation.
R. L. Foltz, A. F. Fentiman, L. A. Mitscher and H. D. H. Showalter, J. Chem. Soc., Chem. Commun., 1973, 872 DOI: 10.1039/C39730000872
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