The use of gold(III) as oxidant provides a method for the sterospecific oxidation of methionine to methionine sulphoxide under conditions that can be extended to biological systems containing sulphides; preliminary kinetic studies give a possible explanation of the sterospecifiction of this reaction.
E. Bordignon, L. Cattalini, G. Natile and A. Scatturin, J. Chem. Soc., Chem. Commun., 1973, 878 DOI: 10.1039/C39730000878
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