Three-co-ordinated transition-metal compounds. Part II. Electronic spectra and magnetism of tris(bistrimethylsilylamido)derivatives of scandium, titanium, vanadium, chromium, and iron
Abstract
The electronic spectra, magnetic susceptibilities, and preliminary e.s.r. data are reported for the trigonal compounds M[N(SiMe3)2]3 where M = Sc, Ti, V, Cr, and Fe. The data are interpreted on the basis of crystal-field calculations for dn systems in D3h symmetry.