Issue 16, 1973
From the journal:

Journal of the Chemical Society, Dalton Transactions

ortho-Metallation and related reactions. Part VI. Triaryl phosphite derivatives of dodecacarbonyltriruthenium

Michael I. Bruce,   Gordon Shaw  and  F. Gordon A. Stone  

Abstract

Reactions between Ru3(CO)12 and P(OR)3 afford the complexes Ru3(CO)12 –n[P(OR)3]n(R = Ph, n= 2 or 3; R =p-tolyl, n= 3). The trisubstituted complexes undergo intramolecular metallation and degradation reactions in refluxing decalin, to give Ru(CO)2[P(OC6H3R)(OC6H4R)2]2[R = H (2 isomers) or Me], Ru2H(CO)3[P(OC6H3R)(OC6H4R)2]2[OP(OC6H4R)2](R = H or Me), and H4Ru4(CO)9[P(OPh)3]3. Possible mechanisms of formation of these complexes are discussed.

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Article information

DOI
https://doi.org/10.1039/DT9730001667
Article type
Paper

J. Chem. Soc., Dalton Trans., 1973, 1667-1672

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ortho-Metallation and related reactions. Part VI. Triaryl phosphite derivatives of dodecacarbonyltriruthenium

M. I. Bruce, G. Shaw and F. G. A. Stone, J. Chem. Soc., Dalton Trans., 1973, 1667 DOI: 10.1039/DT9730001667

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