Issue 18, 1974

Distinctive thermal behaviour of geometrically isomeric oxetans

Abstract

trans-2-Phenyl-3-n-propyloxetan thermolysed at 250–300° to give trans-1-phenylpent-1-ene stereospecifically, whereas the cis-isomer decomposed more slowly (by a factor of ca. 2) to produce a mixture of cis- and trans-olefin.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 734-735

Distinctive thermal behaviour of geometrically isomeric oxetans

N. Shimizu and S. Nishida, J. Chem. Soc., Chem. Commun., 1974, 734 DOI: 10.1039/C39740000734

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