With 2H n.m.r. spectroscopy, it is established that adamantanone undergoes homoenolization with predominant exo β-proton exchange under conditions comparable to those required for a v ariety of polycyclic ketones.
J. B. Stothers and C. T. Tan, J. Chem. Soc., Chem. Commun., 1974, 738 DOI: 10.1039/C39740000738
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