Issue 18, 1974

Polar effects in Grignard attack at the oxygen atoms of carbonyl groups

Abstract

The yields of benzyl ethers relative to those of 4-benzylphenols from reaction of substituted benzylmagnesium chlorides with 6-acetoxy-2,6-dimethylcyclo-hexa-2,4-dienone are unaflected by the nature of the substituents, but the yields of both products increase, relative to those of 3-benzylphenols, with increasing electron-donating powers of the substituents.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 750-751

Polar effects in Grignard attack at the oxygen atoms of carbonyl groups

B. Miller, J. Chem. Soc., Chem. Commun., 1974, 750 DOI: 10.1039/C39740000750

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