The displacement of oxygen from Fe(TPP)(base)(O2) is a dissociative process in which the axial base exerts a trans effect with the lability of the co-ordinated oxygen decreasing in the order pyridine > piperidine >> 1-methylimidazole.
C. J. Weschler, D. L. Anderson and F. Basolo, J. Chem. Soc., Chem. Commun., 1974, 757 DOI: 10.1039/C39740000757
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