Issue 9, 1974

13C nuclear magnetic resonance study of the formation of a cyclopentyl cation from thujan-3-ol

Abstract

In solution in SbF5–HSO3F–SO2 at –50°, 4α-H-thujan-3β-ol forms a cation with the p-menthane structure; in the absence of SbF5, this ion decomposes slowly to yield a 2,3-dimethyl-1-propylcyclopentyl cation.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1974, 353b-354

13 C nuclear magnetic resonance study of the formation of a cyclopentyl cation from thujan-3-ol

C. M. Holden and D. Whittaker, J. Chem. Soc., Chem. Commun., 1974, 353b DOI: 10.1039/C3974000353B

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