Under negative ion chemical ionization conditions, the radical anion of tetrachlorodibenzo-p-dioxin (TCDD) undergoes a novel reaction with oxygen to produce an ion which is characteristic of structure and easily identified in the presence of other halogenocarbon contaminants.
D. F. Hunt, T. M. Harvey and J. W. Russell, J. Chem. Soc., Chem. Commun., 1975, 151 DOI: 10.1039/C39750000151
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