Issue 9, 1975

Novel specific carbon–carbon bond formation; substituent and solvent effects associated with hydride addition to aromatic olefins

Abstract

2,2-Diarylpropanes are conveniently prepared from 1,1-diarylethylenes, lithium aluminium hydride, and anisole in tetrahydrofuran while 1,1-diarylethanes are obtained at 140 °C in bis(methoxyethyl) ether; hydride addition to 1,1-diarylethylenes is decelerated by 2-methyl substituents, and o- and p-methoxy, but not m-methoxy.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 348-349

Novel specific carbon–carbon bond formation; substituent and solvent effects associated with hydride addition to aromatic olefins

I. Granoth, R. Alkabets, Y. Segall, E. Rachaman and H. Leader, J. Chem. Soc., Chem. Commun., 1975, 348 DOI: 10.1039/C39750000348

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