Thermolysis of but-3-enyl substituted 2H-azirines gives substituted pyridines and biphenyl derivatives via 1,4-hydrogen transfer from the methylene group of an intermediate vinylnitrene.
A. Padwa and N. Kamigata, J. Chem. Soc., Chem. Commun., 1975, 789 DOI: 10.1039/C39750000789
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