Issue 19, 1975

Reactive rhodium complexes derived from trans-6-vinylbicyclo[3.1.0.]hex-2-ene. Mechanistic studies and X-ray structure of η4-3,1′–3′(4-allylcyclopent-1-enyl)hexafluoroacetylacetonatorhodium tetramer

Abstract

The title compound forms rhodium(I) complexes with attendant cyclopropane ring-opening, and the resulting acetylacetonates rearrange cleanly above room temperature.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 792-793

Reactive rhodium complexes derived from trans-6-vinylbicyclo[3.1.0.]hex-2-ene. Mechanistic studies and X-ray structure of η4-3,1′–3′(4-allylcyclopent-1-enyl)hexafluoroacetylacetonatorhodium tetramer

N. W. Alocock, J. M. Brown, J. A. Conneely and D. H. Williamson, J. Chem. Soc., Chem. Commun., 1975, 792 DOI: 10.1039/C39750000792

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