Issue 20, 1975

Formation of allyl sulphide synthons by [1,2] and [1,3] shifts of the phenylthio group

Abstract

Allyl phenyl sulphides, made from 2-hydroxy-alkyl phenyl sulphides by acid-catalysed rearrangement of the phenylthio group, may be isomerised by the [1,3] allylic shift of the same group, and converted into 4-hydroxy carbonyl compounds or allyl alcohols.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 820-821

Formation of allyl sulphide synthons by [1,2] and [1,3] shifts of the phenylthio group

P. Brownbridge and S. Warren, J. Chem. Soc., Chem. Commun., 1975, 820 DOI: 10.1039/C39750000820

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