Issue 20, 1975
From the journal:

Journal of the Chemical Society, Chemical Communications

The opening of a C8 ring in a di-ruthenium complex; crystal and molecular structures of [Ru2(CO)5{Me2SiCH2CH2Si(Me2)C8H8}] and [Ru2(SiMe3)(CO)4(C8H8SiMe3)]

Julie D. Edwards,   Richard Goddard,   Selby A. R. Knox,   Ronald J. McKinney,   F. Gordon A. Stone  and  Peter Woodward  

Abstract

The binuclear ruthenium complexes [Ru2(SiMe3)(CO)5(C8 H8SiMe3)] and [Ru2(CO)5{Me2SiCH2 CH2Si(Me2)-C8H8}] contain cyclic η7-C8 ligands; the former on thermolysis affords[Ru2(SiMe3)(CO)4(C8H8SiMe3)], shown by X-ray diffraction to contain a ring-opened η8-C8 ligand.

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Article information

DOI
https://doi.org/10.1039/C39750000828
Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 828-829

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The opening of a C8 ring in a di-ruthenium complex; crystal and molecular structures of [Ru2(CO)5{Me2SiCH2CH2Si(Me2)C8H8}] and [Ru2(SiMe3)(CO)4(C8H8SiMe3)]

J. D. Edwards, R. Goddard, S. A. R. Knox, R. J. McKinney, F. G. A. Stone and P. Woodward, J. Chem. Soc., Chem. Commun., 1975, 828 DOI: 10.1039/C39750000828

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