Issue 20, 1975

Hexagonal close packing of metal atoms in the new polynuclear anions [Rh13(CO)24H5–n]n(n= 2 or 3); X-ray structure of [(Ph3P)2N]2[Rh13(CO)24H3]

Abstract

The [Rh13(CO)24H5–n]n(n= 2 or 3) anions have been isolated from the reaction of the [Rh12(CO)30]2– dianion with hydrogen; they are structurally related to a close hexagonal packing of rhodium atoms having mean distances of 2.81 Å.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1975, 859-860

Hexagonal close packing of metal atoms in the new polynuclear anions [Rh13(CO)24H5–n]n(n= 2 or 3); X-ray structure of [(Ph3P)2N]2[Rh13(CO)24H3]

V. G. Albano, A. Ceriotti, P. Chini, G. Ciani, S. Martinengo and W. M. Anker, J. Chem. Soc., Chem. Commun., 1975, 859 DOI: 10.1039/C39750000859

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