Mono- and di-γδ-unsaturated NN-dialkylthiomides have been synthesized by a thio-Claisen rearrangement of α-amino-αβ-unsaturated sulphides derived from acyclic NN-dialkylthioamides.
S. Takano, E. Yoshida, M. Hirama and K. Ogasawara, J. Chem. Soc., Chem. Commun., 1976, 776 DOI: 10.1039/C39760000776
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