Issue 19, 1976

Intervention of oxygen in the horseradish peroxidase-catalysed oxidtion of aromatic tertiary amines with hydrogen peroxide

Abstract

The horseradish peroxidase-catalysed oxidation of aromatic tertiary amines with hydrogen peroxide leads to a secondary amine and an aldehyde, and with alkylmethylaminilines demethylation is preferred to dealkylation; the reaction depends on the concentration of oxygen in the solution, probably as a cosequence of the generation of peroxides by the reaction of oxygen with the radicals formed.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1976, 782-783

Intervention of oxygen in the horseradish peroxidase-catalysed oxidtion of aromatic tertiary amines with hydrogen peroxide

G. Galliani, B. Rindone and A. Marchesini, J. Chem. Soc., Chem. Commun., 1976, 782 DOI: 10.1039/C39760000782

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