Irradiation of 2-methylene-1,2,3,4-tetrahydro-1,4-methanonaphthalene (I) in acidic methanol leads to three products (II), (III), and (IV); the formation of (II) represents a novel anti-Markovnikov addition of methanol across the methylene double bond.
H. Morrison and T. Nylund, J. Chem. Soc., Chem. Commun., 1976, 785 DOI: 10.1039/C39760000785
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