Two ‘strapped’ porphyrins, containing a chain of atoms linking two opposite meso-positions have been synthesized; their iron(II) complexes were oxygenated reversibly at low temperatures (–55 °C) and at 25 °C were converted, irreversibly, into µ-oxo dimers.
J. E. Baldwin, T. Klose and M. Peters, J. Chem. Soc., Chem. Commun., 1976, 881 DOI: 10.1039/C39760000881
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