Iron(II) phthalocyanine, [Fe(pc)], reacts with tri-n-butyl phosphite and tri-n-butylphosphine to form low-spin bis adducts, [Fe(pc)(PR3)2]. Replacement of P(OBu)3 by PBu3 occurs rapidly and follows a strictly dissociative mechanism.
D. A. Sweigart, J. Chem. Soc., Dalton Trans., 1976, 1476 DOI: 10.1039/DT9760001476
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