The 13C n.m.r. spectra of methyl 2-(3-hydroxy-2-methoxycarbonyl-4,5,6-trimethylphenyl)propionate (II) derived from the fungal metabolite sclerin (I) enriched with 13C from [1,2-13C]acetate or from [methyl-13C]-methionine, establish that the metabolite is derived from two β-ketide precursors with the introduction of three C-methyl groups from methionine.
R. E. Cox and J. S. E. Holker, J. Chem. Soc., Perkin Trans. 1, 1976, 2077 DOI: 10.1039/P19760002077
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...