Enhanced polarisations of several nuclei suggest that the thermal rearrangement of R1R2C![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
N–OS-(O)R3 to sulphonyl imine proceeds partly by a recombination of geminate radical pairs and partly by the scavenging of escaped radicals.
C. Brown, R. F. Hudson and K. A. F. Record, J. Chem. Soc., Chem. Commun., 1977, 540 DOI: 10.1039/C39770000540
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