For both i.r. laser and broad band near-i.r. irradiation of [Fe(CO)4] in a nitrogen matrix at 20 K, the quantum yield for intramolecular isomerization is considerably greater than the quantum yield for reaction with N2.
B. Davies, A. McNeish, M. Poliakoff, M. Tranquille and J. J. Turner, J. Chem. Soc., Chem. Commun., 1978, 36 DOI: 10.1039/C39780000036
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