The nucleophilic decomposition of 1-methyl-heptylbis(dimethylglyoximato)cobalt(IV) by Cl– to form 2-chloro-octane occurs with inversion of configuration at the cobalt-bonded carbon; this is consistent with the view that such a process is a step in the halogen cleavage of metal–carbon bonds.
R. H. Magnuson, J. Halpern, I. Ya. Levitin and M. E. Vol'pin, J. Chem. Soc., Chem. Commun., 1978, 44 DOI: 10.1039/C39780000044
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