The hydrogenation of penta-1,3-diene has been studied over various catalysts (MoS2, ZnO, Cr2O3, and Co3O4) which normally lead to predominant 1,2- rather than 1,4-addition of hydrogen; ZnO led to hydrogenation of the internal double bond with high (87·3%) selectivity, by 3,4-addition.
T. Okuhara and K. Tanaka, J. Chem. Soc., Chem. Commun., 1978, 53 DOI: 10.1039/C39780000053
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