The population ration of the ee and ae+ea conformations in NN′-dichloropiperazine at –45 °C is 3:1 (ΔG°= 0·5 kcal mol–1); this unusually low value possibly arises from a generalized anomeric effect.
F. A. L. Anet and I. Yavari, J. Chem. Soc., Chem. Commun., 1978, 58 DOI: 10.1039/C39780000058
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