Issue 2, 1978
From the journal:

Journal of the Chemical Society, Chemical Communications

Copper derivatives of tetrathiafulvalene

A. R. Siedle,   G. A. Candela,   T. F. Finnegan,   R. P. Van Duyne,   T. Cape,   G. F. Kokoszka  and  P. M. Woyciesjes  

Abstract

Oxidation of tetrathiafulvalene with CuCl2.2H2O in ethanol produced the mixed valence metallotetrathia-ethylene (TTF)3(CuCl2)5 containing both TTF+· and TTF2+, which was converted into (TTF)2 CuCl4 on dissolution in hot acetonitrile while the CuCl42– and BF4– salts of TTF2+ were prepared using CuCl2·2H2O and Cu(BF4)2 in acetonitrile; resonance Raman spectroscopy was used to probe the oxidation state of TTF in these copper metallotetrathiafulvalenes, and e.s.r. and magnetic susceptibility data indicate the presence of three-dimensional magnetic interactions in the TTF+ and TTF2+ CuCl42– salts.

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Article information

DOI
https://doi.org/10.1039/C39780000069
Article type
Paper

J. Chem. Soc., Chem. Commun., 1978, 69-70

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Copper derivatives of tetrathiafulvalene

A. R. Siedle, G. A. Candela, T. F. Finnegan, R. P. Van Duyne, T. Cape, G. F. Kokoszka and P. M. Woyciesjes, J. Chem. Soc., Chem. Commun., 1978, 69 DOI: 10.1039/C39780000069

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