Chloroiodomethane smoothly reacts with triphenylphosphine to yield chloromethyltriphenylphosphonium iodide (1), which in turn can be utilized for the conversion of aldehydes and ketones into chloro-olefins and acetylenes upon treatment with potassium t-butoxide.
S. Miyano, Y. Izumi and H. Hashimoto, J. Chem. Soc., Chem. Commun., 1978, 446 DOI: 10.1039/C39780000446
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