Photolysis of ethyl p-cyanobenzoate in the presence of 2-methylene-1,2,3,4-tetrahydro-1,4-ethano-naphthalene (I) or 2-methylene-1,2,3,4-tetrahydro-1,4-methanonaphthalene (II) leads to anti-Markovnikov addition of solvent (methanol) across the double bond.
D. D. Neidigk and H. Morrison, J. Chem. Soc., Chem. Commun., 1978, 600 DOI: 10.1039/C39780000600
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