Methylenecyclopropane reacts with tram-[PtH(NO3) L2] to give complexes with the (1–3-η-methylallyl)platinum cations [Pt(C4H7)L2]+(L = PEt3, PMe2Ph, or PPh3). When L = PEt3 or PMe2Ph the complexes contain the 1-methylallyl ligand only, but when L = PPh3 the 2-methylallyl isomer is also formed. On the basis of deuterium-labelling studies. mechanisms for these reactions are proposed.
R. L. Phillips and R. J. Puddephatt, J. Chem. Soc., Dalton Trans., 1978, 1736 DOI: 10.1039/DT9780001736
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