The dianion derived from t-butyl N-trimethyl-silylprop-2-ynycarbamate undergoes alkylation and carboxylation at the propynylic position, leading to derivatives of acetylenic amines and amino acids.
B. W. Metcalf and P. Casara, J. Chem. Soc., Chem. Commun., 1979, 119 DOI: 10.1039/C39790000119
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