The binuclear complexes of the type (±)-[(Me3PtX)2MeE(CHR)nEMe](E = S or Se; X = Cl, Br, or I; R = H or Me; n= 0 or 1) have been shown to exhibit a remarkable series of fluxional phenomena over a range of temperatures; most notable of these is an intermetallic commutation by the two donor atoms of the bidentate sulphur and selenium ligands.
E. W. Abel, A. R. Khan, K. Kite, K. G. Orrell and V. Šik, J. Chem. Soc., Chem. Commun., 1979, 126 DOI: 10.1039/C39790000126
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