In the presence of hydrogen on platinum, palladium, and rhodium catalysts, 2,2,4,4-tetramethyloxetan undergoes isomerization to neopentyl methyl ketone via a 1,3-methyl migration; this is the first experimental observation of a 1,3-bond shift isomerization on noble metals.
M. Bartók, J. Chem. Soc., Chem. Commun., 1979, 139 DOI: 10.1039/C39790000139
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