Issue 17, 1979
From the journal:

Journal of the Chemical Society, Chemical Communications

H2Ru6(CO)18,[HRu6(CO)18]–, and [Ru6(CO)18]2–: a simple high yield route to these clusters and the X-ray structure of [Ph3MeP]2[Ru6(CO)18]

Peter F. Jackson,   Brian F. G. Johnson,   Jack Lewis,   Mary McPartlin  and  William J. H. Nelson  

Abstract

Reaction of Ru3(CO)12 with base gives [HRu3(CO)11]– or [Ru6(CO)18]2– depending upon reaction conditions, and acidification of either produces [HRu6(CO)18]– then H2Ru6(CO)18; X-ray analysis has shown the [Ru6(CO)18]2– dianion to possess octahedral metal geometry with bridging as well as terminal carbonyl ligands.

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Article information

DOI
https://doi.org/10.1039/C39790000735
Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 735-736

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H2Ru6(CO)18,[HRu6(CO)18]–, and [Ru6(CO)18]2–: a simple high yield route to these clusters and the X-ray structure of [Ph3MeP]2[Ru6(CO)18]

P. F. Jackson, B. F. G. Johnson, J. Lewis, M. McPartlin and W. J. H. Nelson, J. Chem. Soc., Chem. Commun., 1979, 735 DOI: 10.1039/C39790000735

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