The low-temperature product, [(η5-C5H5)2WH(NNHR)][X](R = aryl, X = BF4 or PF6), from the reaction of [RN2][X] with (η5-C5H5)2WH2 rearranges in solution above –20 °C to yield [(η5-C5H5)2W(H2NNR)][X] in which the arylhydrazido ligand is bound to W in a ‘side-on’ or dihapto manner.
J. A. Carroll, D. Sutton, M. Cowie and M. D. Gauthier, J. Chem. Soc., Chem. Commun., 1979, 1058 DOI: 10.1039/C39790001058
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