The nickel(II) complexes formed from the three novel penta-aza macrocycles (1), (2), and (3) are easily oxidised to the NiIII species both chemically and electro-chemically and the E½ values for the Ni2+/Ni3+ couple are only slightly dependent upon the macrocyclic ring size, in strong contrast with those found for tetra-aza systems.
L. Fabbrizzi, J. Chem. Soc., Chem. Commun., 1979, 1063 DOI: 10.1039/C39790001063
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