Issue 23, 1979

M.c.d. spectra of Cr(CO)5L (L = piperidine, trimethylamine, pyridine, and pyrazine). Evidence for the nature of the lowest excited ligand field state and for steric and electronic influence of L on the symmetry of the complexes

Abstract

With the use of m.c.d. spectra the nature of the lowest ligand field (LF) excited state of Cr(CO)5L complexes (L = N-donor ligand) is characterized for the first time, which is of importance for understanding the photochemical behaviour of these complexes.

Article information

Article type
Paper

J. Chem. Soc., Chem. Commun., 1979, 1075-1077

M.c.d. spectra of Cr(CO)5L (L = piperidine, trimethylamine, pyridine, and pyrazine). Evidence for the nature of the lowest excited ligand field state and for steric and electronic influence of L on the symmetry of the complexes

G. Boxhoorn, D. J. Stufkens, P. J. F. M. v.d. Coolwijk and A. M. F. Hezemans, J. Chem. Soc., Chem. Commun., 1979, 1075 DOI: 10.1039/C39790001075

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